Potassium propanoate

Potassium propanoate
Names
Preferred IUPAC name
Potassium propanoate
Other names
Potassium propionate; E283
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.005.749 Edit this at Wikidata
EC Number
  • 206-323-5
E number E283 (preservatives)
UNII
  • InChI=1S/C3H6O2.K/c1-2-3(4)5;/h2H2,1H3,(H,4,5);/q;+1/p-1 ☒N
    Key: BWILYWWHXDGKQA-UHFFFAOYSA-M ☒N
  • InChI=1/C3H6O2.K/c1-2-3(4)5;/h2H2,1H3,(H,4,5);/q;+1/p-1
    Key: BWILYWWHXDGKQA-REWHXWOFAC
  • CCC(=O)[O-].[K+]
Properties
C3H5KO2
Molar mass 112.1689 g/mol
Appearance Colorless crystalline platelets[1]
Melting point 358 to 366 °C; 676 to 691 °F; 631 to 639 K[2]
soluble[1]
Solubility in ethanol soluble[1]
Thermochemistry
Enthalpy of fusion fHfus)
179 kJ/kg[2]
Hazards
GHS labelling:[3]
GHS07: Exclamation mark
Warning
H302, H317, H319
P261, P264, P264+P265, P270, P272, P280, P301+P317, P302+P352, P305+P351+P338, P321, P330, P333+P317, P337+P317, P362+P364, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Potassium propanoate or potassium propionate is a chemical compound with the chemical formula K(C2H5COO). It is the potassium salt of propanoic acid.

Preparation

[edit]

Potassium propanoate can be prepared by treating potassium carbonate with propanoic acid.[2]

Use

[edit]

It is used as a food preservative and is represented by the food labeling E number E283 in Europe[4] and by the INS number 283 in Australia and New Zealand.[5]

Reactions

[edit]

Decomposition takes place via ketonization, yielding the symmetric ketone (3-pentanone) and potassium carbonate:[2]

2K(O2CEt) → K2CO3 + Et(CO)Et

References

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  1. ^ a b c J. I. G. Cadogan, J. Buckingham, F. MacDonald: Dictionary of Organic Compounds: First Supplement. CRC Press, 1996, ISBN 978-0-412-54110-0
  2. ^ a b c d Bui, Ly Huong; de Klerk, Arno (2014-02-13). "Thermal Behavior of Potassium C1–C12 n-Alkanoates and Its Relevance to Fischer–Tropsch". Journal of Chemical & Engineering Data. 59 (2): 400–411. doi:10.1021/je400874d. ISSN 0021-9568.
  3. ^ PubChem. "Potassium propionate". pubchem.ncbi.nlm.nih.gov. Retrieved 2026-02-01.
  4. ^ UK Food Standards Agency: "Current EU approved additives and their E Numbers". Retrieved 2011-10-27.
  5. ^ Australia New Zealand Food Standards Code"Standard 1.2.4 - Labelling of ingredients". 8 September 2011. Retrieved 2011-10-27.